Impact modification of polypropylene

This paper compares the modification mechanism provided by ethylene‐octene (EO) copolymer to that of ethylene‐propylene‐diene terpolymer (EPDM) rubber. Within the limits of this study, the highest impact strength was achieved at 30–40% rubber content, regardless of the rubber type. An increase in rubber melt viscosity resulted in overall greater impact strength. At the optimum concentration, the high‐viscosity (MFI = 1 to 5) EO rubber provided modification mainly via a crazing mechanism, while the EPDM rubber functioned by energy dissipation through the three‐dimensional network structure formed with the polypropylene matrix. This paper also discusses the effects of the processing conditions on the physical properties of PP/EPR copolymer. An increase in processing temperature and screw speed resulted in a reduced number of discrete rubber particles and nearly no or very slight increase in impact strength, but a very significant reduction in tensile strength and tensile modulus.     

Copper Oxide Precipitates in NBS Standard Reference Material 482

Copper oxide has been detected in the copper containing alloys of NBS Standard Reference Material (SRM) 482. This occurrence is significant because it represents heterogeneity within a standard reference material that was certified to be homogeneous on a micrometer scale. Oxide occurs as elliptically to spherically shaped precipitates whose size differs with alloy composition. The largest precipitates occur in the Au20-Cu80 alloy and range in size from submicrometer up to 2 μm in diameter. Precipitates are observed using light microscopy, electron microscopy, and secondary ion mass spectrometry (SIMS). SIMS has demonstrated that the precipitates are present within all the SRM 482 wires that contain copper. Only the pure gold wire is precipitate free. Initial results from the analysis of the Au20-Cu80 alloy indicate that the percentage of precipitates is less than 1 % by area. Electron probe microanalysis (EPMA) of large (2 μm) precipitates in this same alloy indicates that precipitates are detectable by EPMA and that their composition differs significantly from the certified alloy composition. The small size and low percentage of these oxide precipitates minimizes the impact that they have upon the intended use of this standard for electron probe microanalysis. Heterogeneity caused by these oxide precipitates may however preclude the use of this standard for automated EPMA analyses and other microanalysis techniques.     

Preventing Segregation during Centrifugal Consolidation of Particulate Suspensions: Particle Drafting

Dilute, dispersed, multicomponent suspensions containing Ce-ZrO₂, Al₂O₃, and varying Al₂O₃-platelet contents were centrifugally consolidated. Despite the favorable conditions for segregation, phase and size segregation did not occur in the highest Al₂O₃-platelet content suspension. The suspension properties did not consist of agglomeration, high solids fractions, or high suspension viscosities typically attributed with segregation prevention. Thus, a new mechanism is suggested, considering the effects of hydrodynamic particle interactions (interference drag or "drafting") on particle arrangement during consolidation. Particle drafting is proposed and supported as a mechanism for preventing segregation, and the importance of hydrodynamic particle interactions in ceramic processing is discussed.     

Antioxidant activity of lipid-soluble phenolic diterpenes from rosemary

A high-performance liquid chromatography method for analyzing the phenolic diterpenes present in rosemary (Rosmarinus officinalis L.) and commercial rosemary extracts is reported. Carnosic acid was the major phenolic diterpene present in rosemary leaves, with lesser amounts of 12-methoxycarnosic acid and carnosol. Several commercial rosemary extracts also were analyzed by this method, and in addition to these three compounds other phenolic diterpenes, such as 7-methoxyrosmanol, 7-methoxy-epirosmanol, and rosmanol, were found in some samples. These latter three compounds seem to be artifacts, produced from carnosic acid by oxidation and cyclization. The major phenolic diterpenes were isolated, and their relative antioxidatn activities in soybean oil were measured by the Rancimat. The potency of carnosic acid was more than twice that of any other compound. The antioxidant activity of pure carnosic acid was compared to butylated hydroxytoluene (BHT), butylated hydroxyanisole (BHA), and tertiary butylhydroquinone (TBHQ) and was several times greater than BHT and BHA but less than TBHQ. Nuclear magnetic resonance data for several of the compounds that were incompletely characterized in previous literature are reported.     

Modeling of Lake Ice Characteristics in North America Using Climate, Geography, and Lake Bathymetry

Ice cover records from 128 freshwater lakes in the United States and Canada were analyzed. Multivariable linear regression models, log-transform models, and a combination of the two (the “hybrid” form) were used to express ice-in date, ice-out date, and maximum ice thickness as functions of mean air temperature, latitude, average depth, elevation, and surface area of each lake. Mean air temperatures are for periods from September 1 to December 31 for ice-in dates, February 1 to June 30 for ice-out dates, and September 1 to June 30 for maximum ice thickness. Data for individual years as well as averages (over the record length) for each lake were analyzed. The log-transform formulas proved best for estimating ice-in date, while the hybrid form provided the best models of maximum ice thickness. The linear regression model estimated the ice-out date best. In most cases, mean air temperature and/or latitude were the most influential parameters, followed by elevation. Lake surface area and depth had a small or no influence. R2 values of all equations ranged from 0.50 to 0.92.     

Impacts on Children of a Policy to Promote Employment and Reduce Poverty for Low-Income Parents: New Hope After 5 Years.

The impacts of New Hope, a program to increase parent employment and reduce poverty, were measured 5 years after parents were randomly assigned to program or control groups. New Hope had positive effects on children's school achievement, motivation, and social behavior, primarily for boys, across the age range 6-16. In comparison to impacts measured 2 years after program onset, effects on achievement were robust, but effects on social behavior were reduced. The program produced improvements in family income and use of organized child care and activity settings, suggesting possible pathways by which the New Hope package of policies influenced children's behavior. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Incorporating biomarkers of exposure and genetic susceptibility into smoking cessation treatment: Effects on smoking-related cognitions, emotions, and behavior change.

In this article the authors report on the short-term impact of incorporating biomarker feedback about exposure and genetic susceptibility into minimal-contact quit-smoking counseling (QSC). Four hundred and twenty-seven smokers were randomized to 1 of 3 treatments: (a) QSC, (b) QSC + exposure biomarker feedback (EBF) about carbon monoxide in exhaled breath, or (b) QSC + EBF + biomarker feedback about genetic susceptibility to lung cancer (SBF). We observed significant immediate positive effects of SBF, compared with EBF and QSC, on perceived risk, perceived quitting benefits, and fear arousal. However, at the 2-month follow-up, there were no group differences in quit rates. SBF did lead to significant reductions in the number of cigarettes smoked for smokers who were in the preparation stage. Smokers in the EBF and QSC conditions showed reductions in depressive symptoms by 2 months, but smokers in the SBF condition did not. In the context of QSC, genetic feedback may heighten vulnerability and possibly promote distress, but may not immediately enhance quitting in most smokers. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The role of construct type in vocational differentiation: Use of elicited versus provided dimensions.

Recent studies of vocational structure have demonstrated that experimentally provided vocational constructs are used in less complex, less differentiated ways than are Ss' personally elicited construct dimensions. The possible reasons underlying these differences are addressed in this 2-part study. Results of Study 1 supported significant differences between the use of elicited and provided constructs and ruled out 1 methodological artifact that may have accounted for these differences. Study 2 helped to isolate the personal meaningfulness of the elicited construct as an active agent that accounts for differences in the use of these vocational constructs. Findings of both studies document, for the 1st time, a means of increasing differentiation and converge to suggest the important role of personal meaning in vocational structure. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Composition, process, and performance in self-managed groups: The role of personality.

Using the five factor model with an emphasis on extraversion and conscientiousness, the authors investigated how personality is related to small group processes and outcomes. Graduate students (N ?=?289) assigned to 4- and 5-person teams in 61 groups engaged in a series of creative problem-solving tasks over a period of several weeks. Extraversion was associated with group processes and outcomes at both individual and group levels of analysis. At the individual level, extraverts were perceived by others as having greater effect than introverts on group outcomes. Covariance structure modeling suggested that extraverts induce these perceptions through the provision of both socioemotional and task-related inputs. At the group level, the proportion of relatively extraverted members was related curvilinearly to task focus and group performance. Contrary to expectations, Conscientiousness was unrelated to processes and outcomes at either the individual or group level. (PsycINFO Database Record (c) 2010 APA, all rights reserved)